Nitrogen dynamics and removal in a horizontal flow biofilm r

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Nitrogen dynamics and removal in a horizontal flow biofilm reactor for wastewater treatment是什么意

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比特咖啡 共回答了13个问题 | 采纳率76.9%
在水平流生物膜反应器处理污水脱氮动态
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a portion of the nitrogen source is lost by offgassing 中的offgass是什么意思?
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英语翻译Scheme 1 141IntroductionThe synthesis of nitrogen-contai
英语翻译
Scheme 1 141
Introduction
The synthesis of nitrogen-containing heterocycles such as
indoles has been one of the most active areas in organic
chemistry due to their extensive existence in a great number
of biologically active compounds.1 Among the numerous
methods for the preparation of these azaheterocycles,2
the intramolecular hydroamination reaction represents a
highly atom-economic way and many kinds of catalysts
have been developed for this transformation.3 Recently,as
a continuation of their pioneering work in zinc-mediated
cyclization of 2-ynylphenol or -aniline,Nakamura and coworkers
have developed a novel tandem cyclization/
nucleophilic addition procedure of N-benzyl-protected
alkynylanilines with electrophiles to form indole derivatives
mediated by one equivalent of n-BuLi,ZnCl2,
[Pd2(dba)3] (cat.) or n-BuLi,ZnCl2,CuCN·2LiCl.4
Our group has demonstrated that the use of alkynyl sulfonamides
bearing a more acidic NH permits the use of diethylzinc
instead of the more basic n-butyllithium.5 The
use of this weaker base allows for the generation of a sufficiently
nucleophilic nitrogen anion for cyclization,
while conceding for a broader functional group tolerance.
Moreover,a catalytic amount of diethylzinc was found to
be able to catalyze the cyclization reaction and when an
excess of diethylzinc was used,the resulting indole zinc
salt intermediate could undergo reactions with acid chloride
or halides to form C2,C3-disubstituted indoles.Notably,
the choice of sulfonyl groups as the protecting group
was crucial to effect such a cyclization process and the use
of unprotected primary amine or acyl-protected substrates
all failed in this transformation.5
Scope and Limitations
Firstly,a series of 4-substituted 2-ethynyl-N-tosylanilines
were prepared and studied in the cyclization reaction with
20 mol% of diethylzinc in toluene (Scheme 1,Table 1).In
general,both the substrates with electron-withdrawing or
electron-donating groups could provide the desired indole
derivative products in excellent yields,while a shorter reaction
time was observed for the electron-withdrawing
ones (Table 1,entries 3–7).It was found that both halogen
and nitro group were well tolerated in the reaction.In addition,
compounds with alkyl and functionalized alkyl
substituents on the acetylene terminal (R1) were also tested
under similar reaction conditions and the corresponding
indole products could also be obtained in high yields
(Table 1,entries 8–11).Unfortunately,when the substituent
was TMS,the cyclization was inhibited completely,
affording only the deprotected aniline 1i after 24 hours
(1l/1i = 6:1) (Table 1,entry 12).6
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方案1 141
介绍
heterocycles物理的合成等
吲哚一直是最活跃的地区有机食品
化学由于其广泛的生存在这伟大的号码
生物学活性的compounds.1在众多
这些的合成方法azaheterocycles,2
hydroamination分子内的反应代表了一个
高度atom-economic方式和多种催化剂
已经开发为这transformation.3最近,当
他们的创业的延续zinc-mediated工作
2-ynylphenol或-aniline的环,中村和同事
已经开发了一种新型串联环合/
除了N-benzyl-protected亲的程序
与alkynylanilines electrophiles形成indole衍生品
一种等价的中介,ZnCl2 n-BuLi,
[Pd2 dba课程)[3]((猫)或n-BuLi,ZnCl2 CuCN·2LiCl.4,
我们的团队已经表明,使用炔磺胺类药物
轴承一个更多酸性的尼克-海德菲尔德允许使用diethylzinc
而不是基本n-butyllithium.5
利用这一较弱的基地可以生成一个充分
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虽然有对更大官能团宽容.
此外,催化量的diethylzinc被发现
能够催化环合反应,如果某个
使用超过diethylzinc,产生的indole锌
盐中间可能接受与酸反应效果
或halides形成C2,C3-disubstituted吲哚.值得注意的是,
sulfonyl的选择组)为保护小组
是至关重要的,执行这个环化过程和使用
保护的主要胺和acyl-protected基质
在这个transformation.5都没有
范围和局限性
首先,一系列的4-substituted 2-ethynyl-N-tosylanilines
有准备,并研究了环化反应
20组分diethylzinc的% 1、方案,以甲苯(表1).在
一般来说,都与electron-withdrawing底物
探讨了给电子基团对可以提供需要的indole
衍生产品的产量,而更短的反应
时间为electron-withdrawing观察
(表1,参赛作品的3 - 7).这是发现无论是卤素
和硝基集团都耐受良好的反应.此外,
物质烷基和功能化烷基
在取代乙炔终端(R1)进行了测试
在类似的反应条件和相应的
indole产品也可以获得了丰收
(表1,进入8胜11败).不幸的是,当替代物
是TMS环,完全是抑制,
只提供24小时后deprotected苯胺诗
(= 1 /诗滤)(表1、入境12)6
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英语翻译how much do you need to increase the nitrogen concentrat
英语翻译
how much do you need to increase the nitrogen concentration to affect a nine-fold increase in reaction rate.
特别是nine-fold是什么意思,怎么查也查不到,急,
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nine-fold有两个意思
1 :being nine times as great or as many 九倍于...
2 :having nine units or members 有9个单元或者成员
这句话就是 :你需要把氮浓度增大多少来获得九倍于原来的反应速率
针对你的补充问题:
你说的对,单独的fold词的解释没有倍数的意思,但是它放在数词后面就做倍数解释 词典中是可以查到的 你在fold前面输入“-” 这样就可以查到 点击我的参考资料 可以看到
-fold
suf.
[置于数词后]表示“倍,重”,如:fivefold,manifold,hundredfold
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英语翻译
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英语翻译
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【翻译】空气由氮和氧组成
consists 由.组成
2 C
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B.The number of new cars sold per year in Donia has declined slightly since 1993.
C.Pollutants other than nitrogen dioxide that are emitted by automobiles have also been significantly reduced in Donia since 1993
D.Many Donians who own cars made before 1993 have had catalytic converters installed in their cars.
E.Most car trips in Donia’s capital city are too short for the catalytic converter to reach its effective working temperature.
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is not charged
use
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A
意思:很多气体,包括氮气和氧气,都是没有颜色和气味的
解释 :【including the nitrogen and oxygen in air】作为插入语,可以忽略,然后主语是gases是复数,也是主语,所以缺少谓语,只有A选项有谓语
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