IAL enthalpy change (题目用英文写) 正确答案是B还是D呢,

莫招奴2022-10-04 11:39:544条回答

IAL enthalpy change (题目用英文写) 正确答案是B还是D呢,
高中化学 IAL enthalpy change (题目用英文写)

正确答案是B还是D呢,

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yehelai 共回答了20个问题 | 采纳率85%
D
化学反应的标准摩尔熵变,可由生成物与反应物的标准熵求得
等于生成物的标准熵-反应物标准熵
次题中没有给H2的标准熵
因此无法计算
1年前
ecfed4bmh 共回答了2个问题 | 采纳率
D没有H-H的键能
1年前
到ff都要爱_曲 共回答了2个问题 | 采纳率
D
1年前
味味乐 共回答了1个问题 | 采纳率
d
1年前

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怎么求?
雪村萦子1年前1
王老灌 共回答了12个问题 | 采纳率100%
There're 2 problems in the question:
1.There's no such a thing as cycloproane (C3H8),The formula of cyclopropane is C3H6.
2.Even if it asked to calculate the enthalpy change of formation of C3H8,its enthalpy change of combustion is still needed.I checked myself,the enthalpy change of combustion of C3H6 is -2091.4 kJ/mol,very close to -2090 kJ/mol in the question.Therefore,C3H8 was an error.If that's the case,the enthalpy change of combustion of H2 is needed,which is -286 kJ/mol.
(i) 3C (s) + 3O2 (g) = 3CO2 (g) ∆H₁ = (-393.7)*2 = -1181.1 kJ
(ii) 3H2 (g) + (3/2)O2 (g) = 3H2O (l) ∆H₂ = (-286)*3 = -858 kJ
(iii) C3H6 (g)+ (9/2)O2 (g) = 3CO2 (g) + 3H2O (l) ∆H₃ = -2090 kJ
(i) + (ii) - (iii):3C(s) + 3H2 (g) = C3H6 (g)
∆H = ∆H₁ + ∆H₂ - ∆H₃
= -1181.1 - 858 - (-2090)
= 50.9 kJ/mol